氯化钠在水、水溶液及有机溶剂中溶解度和相关相图.docx

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1、SQLlIbilitL摘要:氯化钠在水、盐酸、硫酸、氯化钙溶液、氯化镁溶液、硫酸钠溶液等无机溶剂中溶解度,相图。氯化钠在甲醉、乙醇、丙醇、丁醇、毗咤、乙二醇、DMF、DMS0、THF等溶剂中的溶解度。目录1氯化钠在水中的溶解度12氯化钠在盐酸中溶解度33氯化钠在硫酸中的溶解度44氯化钠与氯化钙在水中的互溶度,相图45氯化钠与氯化镁在水中的互溶度,相图56氯化钠与氯化镁在水中的互溶度,相图67氯化钠在其它无机溶剂中的溶解度108氯化钠在甲醇中的溶解度119氯化钠在乙醇及乙醇溶液中的溶解度1110氯化钠在其它有机溶剂中的溶解度121氯化钠在水中的溶解度温度()溶解度(g100g水)-21.230.

2、4-2030.7-1531.9-1033.2-534.4035.71035.82036.02536.13036.34036.65037.06037.37037.88038.49039.010039.311839.814042.116043.618044.920046.030060.040087.3500122.225G10203040浓度M2氯化钠在盐酸中溶解度1T-27热化在酸中的溶度(周相N.C】)_M-%密BtRcm,液度,%gcm,浓度.%密HanHClINaClHCINaCIHCINaO。12.4901.2079.312.041.141I1.3824.1123.”3.151.2214

3、.6811.921.17250.672S.30一22.534.401.2262.8621.711,1950.6625.301.20220.05.741.232.7521.94一0.3025.971.20418.51.471.2491.523.701.19020.491.207,1.26”.921.295IOC1.S623.72一I0.9524.6一。26.33一1.1724.)4一0.7S25.04-加七M.030.091.185327.880.501.1380f.Xt1!.31.135635.Sl0.121.174720.Ot2.7S1.116Q5.5it.041.1S94SO.41。.”1

4、.150419.922.71.1ISX2.6122.951.179729.110.391.144315.806.10l.1170.5925.371.1935n.s0.421.143415.496.131.1170.0026.431.1980254C30.200.30M497I18.873.551.J15510.1112.001.135829.830.331.1481(17.04.811.H638.8913.571.141926.580.671.1337I14.377.261.12107.08)6.091.151823.451.411.122513.378.231.12365.0318.871.

5、163423.001.481.121811.7110.031.12912.9021.901.176820.322.61.1164I10.901.201.1329;0.0026.471.19839CJ9.620.0N.CI0.655.0NaCl0.656.6NaeI+ccu-zwq056.9UCl22H2O7527.450NaCI1.740.0NaCI1.050.0NaCI0.9.55.0NaCl2 Xo-Z5氯化钠在氯化镁溶液中的溶解度(相图)MCt.HtO、-4L01020304047图 1 30 C、35 (.和 70 C 下 MgCI? NaCl HQ体系的相图HtOM0s(Wt)S2M

6、gCILNaCI-HQ体系3OC、35C、1O5C的相图表1MgCkNaCI-Hq体系在3OC、35C和70C的溶解度IC液相组成(Wt%)固相MgCl2NaCl3035.900.00MgCI26H2O35.790.92MgCI26H2ONaCI28.102.98NaCl24.693.51NaCl18.867.86NaCI5.9920.16NaCl2.9323.49NaCI0.0026.45NaCl3536.210.00MgCi26H2O35.900.68MgCl26H2O+NaCl31.751.26NaCl28.512.65NaCI19.806.72NaCI14.5510.90NaCl5.0

7、521.20NaCl0.26.74NaCl7039.000.00MgCI26H2O38.140.20MgCl26H2O+NaCl30.490.40NaCl5.1021.78NaCl0.QQ26.92NaCl6氯化钠与硫酸钠溶液的互溶度(相图)O,H0J-,OS三NCHOI*OSrNOrHOlZPQtIQ9tilStltOZ9”|IO1.Z19ZCI901.l2eOrItIOS%A+OtHZ6NI三OdSl9S6!,ZCS06TSc6CtttO*Q9L01OOI09Z6KO9O89gZ+,H0S8K一S8SB丁69z*SS19t06rCZgrO1HOI*os,三n+o1h2o*n一09813北8

8、1919I961t8OiZ6ZszDOI06909cOtSZ“一)X45g。,OOl0P00eOi*?+OeHClOSrrZ一99988L9ZSIZQZZ9106IS9CCO,H0*OSe*N+cH2l3N*三SWT6-196FSOIZszOZrNOtHZ”8ZWClOOt09OS09ZSO4*ZW*一orz(MH0I20ZOrzJR+O01tOSxN01。9F609*02It01O99IZO1HOlrOS*NO,H2l3W一mz66WZ9,ZS00OCIZOOF4O,HCNSS!X010r9,0toOtZ(M-*+OXHOl*OS,*K+eH2I三K一SSlZSe6oz,o99100KtxO

9、8eZZzu-O8H6Z78、Z6KZos,三raz,os、ZIONdKW蜜08%E+6Z)QO100/(OlUouI/tomOcHiOOtS取我片W第WC999Wtx*ttOSH99ZIZIlIlSl41,11HlOSN622*lLUl9U10,91002Cll(,BUZ9,ZIM,WM610,11OS、Nm,tZZrn,OSNmi*IZ99lS0,6ZMZIM,Z971VZUB6,6WlC99lco:2,OS,NISWl66SIL9iLS9tlM*6V99IlKCO,,“HWU,OSK+*NW*l6291:,08rzSrOS,36SKI86WJC6S*9oraONUU,IM,SOZRN60

10、CI2991W98sr017$8SrMM,9I9*11,“XOHtON2912*1StII5SN6er,ZCaC94WmHtS0H9Z0S2N4U*ISI,I2l9213*NZoOrlSI8IOWIOXT,SSO:,SICO09CO9,MSZ协0,HOqNZOS、NN:osnKOS%NNOS、NAN俳IQ(0S%N+XN)IoIUoMou0*HPOOOI(wo*w%三中VWSW(M-Z),*互3+*天*aout.52.28036.6605S.95O100182。NaCJ24.2.4734.21.4052.74.3192.41765NaCl+NajSO5.9OS5.301001810Naa24.

11、53.6SX.05.0462.46.3989.117001.222NaCl22.57.3832.010.53.3578.715951.246NaCINtSO420.4九1628.913.0044.51.S73.H1S40t.24SNatSO,+NatSOT0H13.78.7617.711.327.S14.166.524051.187Na1SO4.10lO7.9110.599.6919.0U.9!6.67.63185t.16Na,SO4.IOHsQ016.2019.3024.604085J.151Na1SO4-IOH1Qa度P液相度比&相%g/1OOfeHlOmol100OmolHtOmot)0

12、0raol(Na11Na1SOl)NaClNft1SOlNaClNaxSO.JNaClNaISa2NaC:HtO2126.6O36.2O66.8O10017951.198NaCl24.63.3834.24.6552.76.9089.917051.216NaeJ22.657.0632.310.0549.812.757.16001.241NaCl+NajSOt18.410.425.al7.031.4【8551.247NaaSO4031.846.6069.1016901.304NajSO475W.4037.058.?O100UtS1.178NaCl26.42.143,93.005.9.SO9S.71

13、6501.189NaCl25.264.9535.157.1055.78.0088.115451.207NaCHNa皿1.510.222.514.034.717.766.1180SN三sSO47.7619.710.727.216.S34.532.3I960一NajSO4030.3043.50SS.2018151.270NAiSO410028.0039.0060.101001*551.164NaCl27.11.843B.32.6059.08.30B4.7ISOo1.177NaCl25.9olNaCJ+Na1SO4)NaClNaO4NaCINatSO12NrC)Ka2SO42MaClILUUO27.

14、64.850.87.262.99.187.31390Nx1SOl22.67.2532.2J0.349.6J3.079A1595Na2SO418.858.826.1)2.240.2)5.572.21795Na3SO414.6511.9520.016.330.820.759.81940NatSO47.119.59.726.6)4.933.730.72055Na3SO43.4524.34.833.67.42.614.82000Na2SO420022.458.7532.612.750.2H.175.71505NatSO.15.6513.3522.018.833.923.8讳.71730NaJSO15.

15、2512.9521.218.032.722.8689JbOONaxSOl11.216.7515.523.223.929.444.8IS75NaaSO47.120.559828.415.136.029.5955Na2SO43.5525.655.036.07.745.614.41875NafSO425020.8511.230.7)6.547.320.969.3H6Ma3SO416.112.8522.718.135.022.960.41725NajSO,2.0515.7516.7Zl.825.727.648.21875Na3SO410.9516.616.122.923.329.044.5!910Na

16、JSa7.920.2U.028.1!6.935.632.219C0NatSO45.8521.758.130.012.638.024.71980Na1SO43.824.455.334.18243.216.91945NaJSo430022.1511.733.517.751.622.469.7Y350NaJSO42】811.2532.615.830.221.370.21400NaJSo418.312.2626.317.640.522.364.51690NaeSO,15.1512.2520.9!6.932.221.460.01865Na1SO414.2512.75J9.517.530.022.257.

17、61915NasSO410.313.45JS.517.620.822.348.22320Na1SO47氯化钠在重水及其它无机溶剂中溶解度溶剂温度()溶解度(g100g溶剂)氧化笊(重水)029.22030.15031.310033.9液氨-304.2液氨012.9液澳250.OOl二氧化硫00.016液体二氧化碳不溶液氯不溶8氯化钠在甲醇中的溶解度溶剂温度(C)溶解度(g100g甲醇)甲醇201.41251.39301.37401.31501.27601.229氯化钠在乙醇溶液中的溶解度溶剂温度(C)溶解度(g100g溶剂)30%乙醇溶液1517.5140%乙醇溶液1513.2550%乙醇溶液

18、159.7760%乙醇溶液155.9675%乙醇溶液140.66175%乙醇溶液380.73675%乙醇溶液711.03395.5%乙醇溶液150.17495.5%乙醇溶液77.20.171100%无水乙醇18.50.06510氯化钠在其它有机无机溶剂中的溶解度溶剂温度()溶解度(g100g溶剂)乙二醇1.846.4乙二醇257.15甲酰胺259.4甲酸95%19.75.8甘油258.2N-甲基甲酰胺253.2乙醇胺251.86DMSO250.5乙二胺250.33四氢吠喃250.0225丙醇250.012异丙醇250.0027异丁醇200.0022异丁醇300.0023异丁醇400.0027异丁醇500.0028正丁醇200.005正戊醇200.002正己醇200.0011,4-二氧六环250.0

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