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1、陕西锌业有限公司自行监测方案(2024年)一、企业简介陕西锌业有限公司位于商洛市沙河子镇,公司拥有年产20万吨/年电锌及其配套焙烧烟气制酸生产线、20万吨/年电锌废渣综合回收生产线;为响应国家号召,也为企业自身发展需要,公司一直十分重视环境保护工作,严格按照国务院办公厅关于印发控制污染物排放许可制实施方案的通知(国办发(2016)81号)、环境保护部关于印发排污许可证暂行规定的通知(环水体(2016)186号)、陕西省排污许可证管理暂行规定实施细则及其他相关的环境保护法律、法规、制度和技术规范等文件的要求。遵照铅锌冶炼行业排污许可证申请与核发技术规范对企业生产设施、治污情况和污染物许可量进行了
2、详细录入确定。二、企业生产情况简介陕西锌业有限公司生产原料为锌精矿,通过高温焙烧产生焙烧烟气和氧化锌焙砂,烟气经两转两吸生产硫酸,焙砂经湿法炼锌生产主产品电锌,产能为20万吨/年。正常生产状态,年消耗锌精矿约38万吨(含锌约48%),氧化锌焙砂(采购)约8万吨左右,年消耗水量350万吨左右。三、企业污染物排放执行标准及限值陕西锌业有限公司属于锌冶炼、其他基础化学原料制造企业,污染物排放大气、废水执行铅、锌工业污染物排放标准GB25466-2010,重金属执行(汉丹江流域(陕西段)重点行业水污染排放限值;生活污水执行污水综合排放标准GB8978-1996表4标准;厂界废气监测执行铅锌工业污染物排
3、放标准GB25466-2010表6;渣处理车间(西区)属于无机化学工业,执行无机化学工业污染物排放标准GB31573-2015表3和表5。附表1执行排放标准及限值序号项目类别项目名称执行标准排放限值备注1废气污染物二氧化硫铅锌工业污染物排放标准GB25466-2010表5400mgm32颗粒物80mgm33硫酸雾20mgm34铅及其化合物8mgm35汞及其化合物0.05mgm36氮氧化物大气污染物排放标GB16297-1996表2240mgm7废气污染物(氧化锌西区回转窑排放口)二氧化硫执行无机化学工业污染物排放标准GB31573-2015表3。400mgm38颗粒物30mgm39硫酸雾20m
4、gm3铅及其化合物2mgm3汞及其化合物0.01mgm3氮氧化物200mgm3硫化氢10mgm3氯(氯气)5mgm3氯化氢10mgm3氟化氢0.3mgm3碑及其化合物0.5mgm3镉及其化合物0.5mgm3锌及其化合物5mgm3氨(氨气)20mgmi钝及其化合物0.05mgm37废水污染物PH值铅锌工业污染物排放标准GB25466-2010表26-98化学需氧量60.Omg/19氨氮8.0mg/110悬浮物50.0mg/111硫化物1.0mg/112氟化物8.0mg/113总氮15.0mg/114总磷1.0mg/115总锌汉丹江流域(陕西段)重点行业水污染排放限值DB61/942-2014表3
5、1.0mg/116总铜0.2mgl18总银0.35mgl19总铅0.15mg/120总镉0.015mg/121总汞0.007mg/122总种0.07mg/123总铭1.0mg/124生活污水PH值污水综合排放标准GB8978T996表46-925氨氮15mgl26化学需氧量100mg/127悬浮物70mg/128生化需氧量20mg/1动植物油10mg/129硫酸雾铅锌工业污染物排放标准GB25466-2010表60.330TSP(总悬浮颗粒物)1.031二氧化硫0.532厂界大气铅及其化合物0.006汞及其化合物0.0003噪声(昼间)工业企业厂界噪声排放标准GB12348-20083类区昼间
6、65分贝33噪声(夜间)夜间55分贝厂界大气(氧化锌车间西区原东升公司厂界)碑及其化合物执行无机化学工业污染物排放标准GB31573-2015表5。0.001铉及其化合物0.001氨(氨气)0.3氟化氢0.0024硫化氢0.03四、自行监测项目及频次公司委托陕西中测检测科技有限公司负责公司污染源排放监测,监测点位、监测项目、频次见附表2表2大气排放口基本情况表序号排放口编号排放名称污染物种类排放口地理坐标(1)排气筒高度Gn)排气筒出口内径()(2)排气温度CO生产设施许可编号生产设施企业内部编号生产设施名称主要生产单元名称主要工艺名称监测频次其他信,息排放类型备注经度纬度1DA1191睁化罐
7、废气排放硫酸霎IIOF5.95334941.56150.3常温MFoI34HFOlOl净化罐SCX002常规浸出法1次/季度一般排放口2DA12049#浸出耀废气排放口硫酸霎IlOF4.76334941.59”150.3常温MF0072MF0039浸出罐SCX002常规浸出法1次/季度一般排放口3DAl2148#浸出耀废气排放口硫酸霎11014.69334941.63”150.3常温MF0064MF0031浸出耀SCX002常规浸出法1次/季度一般排放口4DAl22熔炼废气排放口颗粒物110Iz11.42”33。沙48.22”150.3常温MFO818MF0820MFO823MFo825熔炼炉
8、铸型炉soo2常规浸出法1次/季度金银回收车间一般排放口5DA12346蹑出罐废气排放口硫酸IlOF4.44334941.59150.3常温MF0070MF0037浸出耀SCX002常规浸出法1次/季度一般排放口6DAl2447蹴出耀废气排放口硫酸霎HO*4.66334941.63150.3常温MF0061HF0028浸出罐SCX002常规浸出法1次/季度一般排放口7DAl252#净化罐废气排放硫酸霎IlOF6.42334941.59”150.3常温MF0U7MFOO84净化罐SCX002常规浸出法1次/季度一般排放口8DAl2645#浸出耀废气排放口硫酸霎UOF4.40334941.63”1
9、50.3常温MF0057MP0024浸出耀SCX002常规浸出法1次/季度一般排放口9DAl2744#浸出耀废气排放口硫酸霎IlOF4.37334941.59”150.3常温MF0060MFoO27浸出罐SCX002常规浸出法1次/季度一般排放口10DA12843#浸出罐废气排放口硫酸霎11014.19334941.63150.3常温MF0089MFOO56浸出罐SCX002常规浸出法1次/季度一般排放口11DA12942#浸出罐废气排放口硫酸霎11014.40334941.05150.3常温MF0081MF0048浸出罐SCX002常规浸出法1次/季度一般排放口12DAl30锌粉筛分废气排放
10、颗粒物110Iz11.35334943.90150.655MFo769MF0771MFo772MF0770MFO774MFo776MFo775筛分机SCX002常规浸出法1次/季度一般排放口13DA131注型环节废气排放口颗粒物11013.76334940.48150.645MF0778MFMFO783MFo7注型炉SCX002常规浸出法1次/季度锢回收车间一般排放口14DA13241#浸出罐废气排放口硫酸霎110J4.2233049y41.20150.3常温MFOO83MFOO5O浸出罐SCX002常规浸出法1次/季度一般排放口15DAl331#除杂耀废气排放硫酸霎IlO0041.11330
11、49y53.08150.3常温MFO789MFo794除杂罐SCX002常规浸出法1次/季度一般排放口16DA1342#氧化锌炉废气排放口颗粒物1100Oz57.71334950.09150.655MFo828MF0833氧化锌力SCX002常规浸出法1次/季度一般排放口17DAl353#净化罐废气排放硫酸霎IlO0Iz6.64334941.59150.3常温MFOllOMFoO77净化罐SCX002常规浸出法1次/季度一般排放口18DAl36注型蒸憎环节废气颗粒物IlO0Oz42.3033*4953.51150.6常温MF0803MF0801MF0802MF0800MFO808MFO806M
12、FO805蒸憎炉注型炉注型炉SCX002常规浸出法1次/季度镉回收车间一般排放口19DAl3740#浸出耀废气排放口硫酸霎IlO0Iz4.1933*4941.27150.3常温MFoo79MF0046浸出罐SCX002常规浸出法1次/季度一般排放口20DAl38感应炉废气做口颗粒物110J12.83334946.31150.660MFo768MFO773感应电夕SCX002常规浸出法1次/季度一般排放口21DA1394#净化罐废气排放硫酸震110Iz6.78334941.59150.3常温MF(HI4MFOo81净化耀SCX002常规浸出法1次/季度一般排放口22DAl405#阕匕耀废气排放疑
13、客110J6.78334941.56150.3常温MF0106MF0073净化罐SCX002常规浸出法1次/季度一般排放口23DAl416#净化罐废气排放硝寰1107.46334941.56150.3常温MFOl16MF0083净化罐SCX002常规浸出法1次/季度一般排放口24DAl427#净化罐废气排放塞IlO07.36334941.63150.3常温MFOl15MF0082净化罐SCX002常规浸出法1次/季度一般排放口25DAl4339#浸出耀废气排放口询霎1104.12334941.23150.3常温MF0088MFoO55浸出耀SCX002常规浸出法1次/季度一般排放口26DAl4
14、46#置换罐废气排放疣酸雾110*Oz40.57334952.32150.3常温MF0798MFO803置换罐SCX002常规浸出法1次/季度一般排放口27DAl457#置换耀废气排放霎o040.57334952.10150.3常温MF0799MFO804置换罐SCX002常规浸出法1次/季度一般排放口28DAl468#净化罐废气排放硫酸零IlO0Iz7.36334941.59150.3常温MF0108MFOo75净化罐SCX002常规浸出法1次/季度一般排放口29DAl4738#浸出罐废气排放口IIOq13.97334941.16150.3常温MF0058MF0025浸出罐SCX002常规浸
15、出法1次/季度一般排放口30DAl483#制酸系统废气排放口汞及其化合物,铅及其化合物,IlOe044.28”3349z43.03451.255MFOO妁MF0016制酸系有SCX002常规浸出法1次/月小硫酸二期主要排放口颗粒物,二氧化硫1次/小时主要排放口在线监测硫酸黛1次/季度一般排放口31DAl49争化罐废气排放硫酸零11001,7.5433049,41.52”150.3常温MF0103MF0070净化猴SCX002常规澧出法1次/季度一般排放口32DAl5037嗨出整废气排汕口硫酸零110Iz3.9433049,41.23150.3常温MFoO76MF0043澧出罐SCX002常规漫
16、出法I次/季度一般排放口33DA15110*净化搀废气排液口硫酸雾IlOoIz7.6833049,41.12150.3常温MF0095MF0062净化罐SCX002常规澧出法1次/季度一般排放口34DA15236瑁出罐废气排硫陂零110Iz3.7633。49,41.20150.3常温MF0071MF0038澧出罐SCXOO2常规澧出法1次/季度一般排放口35DAl5335就蔓出耀糜气排的口硫酸雾110Iz3.6833049,41.23”150.3常温MFOo67MF0034漫出*SCX002常规澧出法1次/季度一般排放口36DAl5434卡受出援鹰气排硫酸零110Iz3.6133049z41.
17、27150.3常温MFCIo87MFoO54浸出罐SCX002常规澧出法1次/季度一般排放口37DAl5533常夏出擢废气排液口硫酸雾110Iz4.1933049,41.59150.3常温MFoo56MF0023澧出罐SCX002常婉澧出法1次/季度一般排放口38DAl56感应炉2#废气排放颗粒物110Iz10.96”33049,40.91150.645MF0712MF0713MF0715MFo708MFo709MF0711感应电如SCX002常规澧出法1次/季度锌电解车间一般排放口39DAl5732瑁出樨废气排酒口硫酸零IlOoIz4.0833049,41.52150.3常温MF0073MF
18、0040澧出罐SCXoo2常规澧出法1次/季度一般排放口40DAl5853常曼出隆废气排液口硫酸雾110Oz41.2233049,53.29150.3常温MF0786MFO773感应电ItfSCX002常婉澧出法1次/季度一般排放口41DAl593,融墀废气排油口硫酸零110Iz4.2633049,41.56150.3常温MF0075MF0042漫出罐SCX002常规澧出法I次/季度一般排放口42DA16011#净化握废气排的口硫限零110Iz7.8633049,40.98”150.3常温MFoI31MF0098净化建SCX002常婉漫出法1次/季度一般排放口MF0059澧出罐SCX002常规
19、浸出法1次/季度一般排放口MF0026澧出罐SCX002常规浸出法1次/季度一般排放口MF0798羞换罐SCX002常规浸出法1次/季度一般排放口MF0788漫出罐SCX002常规浸出法1次/季度一般排放口MF0052漫出灌SCX002常规漫出法1次/季度一般排放口MF0064净化灌SCX002常规浸出法1次/季度一般排放口MF0035漫出灌SCX002常规浸出法1次/季度一般排放口MFO799蚩换灌SCX002常规浸出法1次/季度一般排放口MF0746MF0747MFo715多服炉多膛炉回转至SCX002常规漫出法1次/月回转亩多膛炉主要排放口1次/小时在线监则1次/季度HF0796除杂豳S
20、CX002常规演出法1次/季度一般排颉口MF0053演出豳SCX002第规漫出法1次/季度一般排放口MF0013沸膑焙仁SCX002常规漫出法1次/季度一般排放口MF0080净化灌SCX002家规浸出法1次/季度一般排液口43DAl6130第曼出罐废气排J硫酸雾110Iz4.1S”33049,41.66150.3常温MF009244DAl6229送矍出罐废气排/口硫酸雾110Iz4.1933049,41.56*150.3常温MF005945DAl631#堂换整废气排放硫酸雾IlOoOz41.0433049,52.79”150.3常温MFo79346DAl64SO嫉蔓出罐废气排琳(口硫酸雾110
21、Oz41.1133。49,53.15”150.3常温MF078347DAl6528*1出盛磨气排/口硫酸雾110Iz4.0133049,41.59150.3常温MF008548DAl6612就争化罐废气排液口硫酸雾IlOoIz7.7533049,41.05150.3常温MF009749DAl6727嫉蔓出罐废气排/口硫酸雾110Iz4.0833049,41.59150.3常温MF006850DAl682#S换雅废气排放硫酸雾110Oz41.0833049,52.72*150.3常温MFo79451DAl69回转星施气排放口汞及箕化台物,铅及其化合物,1101,7.8633049,47.64”4
22、5255MF0750MF0751MF0719颗粒物,二氧化硫硫酸雾52DAlTO3榔余杂罐废气排放硫酸雾110Oz41.00”33049,52.86IS0.3京&MF079153DA17126笼灵出猴历气排T硫酸雾110。Iz3.8633049,41.52”150.3?;:i1MF0086S4DAl722桧弗腾焙烧炉下料口废气排r颗粒物IlOo0,48.1033049,41.70150.660MFoO4655DAl7313就争化罐废气排液口硫酸雾11001,7.6433049,41.20”150.3常温MF0U34a2XlZ56DAl7414#;争化罐废气排T硫酸雾IloOIz7.61*33。
23、49z41.12150.3重温MFO120MF0087:争化耀SCX002常规演出法1次/季度一能排Jrt口57DAlTS15武争化罐废气排/口他喊容I1001,7.43”33049z41.12”150.3常温MFOlOlMF0068:争化耀SCX002常规漫出法1次/季度一般排放口58DAl7616第争化罐废气排/口硫酸雪IlOoIz7.43”33049,41.05”150.3MF0107MF0074:争化罐SCX002常规漫出法1次/季度一般排放口59DAlTT4*三换援窗气排放口硫酸雾IlooOz40.9733049z52.5。”150.3常温MF0796MF0801麦换罐SCX002常
24、规浸出法1次/季度一般排放口60DAl78机板熔铸废气排放口颗粒物110Oz37.91”33049,52.61150.6常温MF0774MFMF0779MF01工频炉HSCX002常规浸出法1次/季度极板车区一般排放口61DAl7917#:争化灌废气排液口硫酸雾IlOoIz7.2833049z41.09”150.3常温MF0099MF0066净化魔SCX002篇视浸出法1次/季度一般排放口82DAl8025能要出罐废气排h!11硫酸雾110Iz3.7633。49z41.56”150.3常温MF0078MF0045漫出罐SCX002常期浸出法1次/季度一般排谈口3D1124能旻出罐庞气排硫酸喜I
25、lOo13.5833049z41.63”150.3常温MF0082MF0049浸出罐SCX002常期漫出法1次/季度一般排谈口64DAl8218*净化罐废气排EM1硫酸套11001,7.1033。49,41.09”150.3常温MFO126MF0093净化耀SCX002常规演出法1次/季度一做排谈口85DAl83感应炉1#废气排油颗检物110Iz10.0933。49z41.02”150.645MF0714MFOTlO感应电灯SCX002常规演出法1次/季度锌电解车间一般排敢口66DAl8423留县出罐底气排HU硫酸雪110Iz3.6533。49z41.52”150.3常温MFOo63MF003
26、0混出摊SCX002常规漫出法1次/季度一般排谈口67DAl853越弗膨焙烧炉下料IS气排放口颗粒物IlOOOz46.69z,33049,42.56150660MFOO45MF0012:欢腾水言好SCX002常规漫出法1次/季度一般排放口88DAl8619*:争化罐废气排fc硫酸雾IlOe1,7.1033049z41.09IS0.3常温MF0121MF0088:争化罐SCX002常规浸出法1次/季度一般排放口69DAl8751能旻出耀医气排硫酸雾110Oz41.18”33。49z53.26150.3常温MF0784MF0789浸出罐SCX002篇版浸出法1次/季度一般排试口70DAl8820*
27、:争化罐应气排11i11硫酸雾110Iz7.07”33。49,41.12*150.3常温MF0102MF0069净化罐SCX002常期浸出法1次/季度一般排成口71DAl8922我登出港庞气排T硫酸秀110Iz3.我,33049z4166150.3学温MF0093MF0060演出程SCX002常规道出法1次/季度一旗排口72DAl903夜化蚌炉废气排T颗粒物IlOoOz57.82”3349,50.12”150.655HF0826MF0831冢化捽力SCX002常规漫出法1次/季度一般排地口73DA19121至要出耀由气排硫酸零110Iz3.1133。49,41.63”150.3常温MF0094
28、MF0061漫出罐SCX002常婉演出法1次/季度一般排淡口74DAl9220拒登出港底气排硫酸案110Iz3.(XT,3349z4159150.3堂温MF0080MF0047漫出摊SCX002常坂漫出法1次/季度一旗排就口75DAl93气排j口颗粒物110Oz539333。49/3983150.6堂温MF0054MF0021球虐机SCX002堂城演出法1次/季度焙砂球磨一般排试口76DA19421#:争化罐废气排/口硫联驾110Iz7.0(Tz33049/41.12150.3MFO124MF0091:争化摊SCX002常版浸出法1次/季度一短排放口TTDAl9522#:争化罐废气排J硫酸雪I
29、lOo1,6.893349z41.09”150.3常温MF0096MF0063净化维SCX002京规法出法1次/季度一般排放口78DAl96Ig茏会出耀廉气排i硫酬费11001.2.93”33。49/41.59”150.3常温MFOO84MF0051道出罐SCX002常婉凌出法1次/季度一做排放口79DA19752统会出灌废气排r硫酸案110Oz41.1133049zS3.18”150.3常15&MF0785MF0790漫出摊SCX002常规浸出法1次/季度一s排放口80DAl9823第争化罐废气排的口硫酸雪110Iz6.7833。49z41.09”150.3常温MF0128MF0095:争化
30、维SCX002常规浸出法1次/季度一般排放口lDAl9910*登出程庞气排硫酸霁110Iz4.0433049z41.05”150.3常温MFOO65MF0032漫出罐SCX002常婉谩出法1次/季度一般排谈口82DA20012凳登出凝废气排曲口硫限变110Iz3.7V,33049/41.05150.3堂温MF0090MF0057漫出程SCX002常颊漫出法1次/季度一般排触口83DA20155嫉要出罐I三气排/口硫酸雪IlOoOz41.25”33049,S3.40”150.3/温MF0788MFo793浸出维SCX002常规浸出法1次/季度一般排放口84DA20211至豆出辗废气排f硫酸需11
31、001,4.4433049z41.27”150.3常温MF0830MF0839漫出融SCX002常期道出法1次/季度一般排放口85DA2039给县出罐底气排放硫酸案110Iz3.7633049/41.02150.3MF0829MFO838濯出罐SCXOo2常扳漫出法1次/季度一酸排的口86DA2042梆余条融废气排放口硫酸等110Oz41.08”33049z52.93”150.3常温MF0790MF0795除杂耀SCX002章规浸出法1次/季度一般排放口U-I87DA205544受出a废气排硫酸零110Oz41.1833049,53.29”150.3常温MFO787MF0792:具出港SCX0
32、02常规浸出法1次/季度一般排放口88DA2062巡酸系统底气排放口汞及其化合物,诺及其化合物.IlOoOz43.9933049,41.84451.155MF0048MF0015制酸系与SCX002常瓶澧出法1次/月小硫酸-期主要排放口颗粒物,二氧化磕1次/小时在线监双硫酸雾1次/季度89DA20724#净化雅废气排T硫酸零IlOo1,6.78”33049z41.09150.3常温MF0129MF0096净化辗SCX002常规漫出法1次/季度一船排放口DA20825#净化罐废气排放口硫酸雾IlOo1667”33049,41.05150.3常温MF0130MF0097净化罐SCX002常规漫出法
33、1次/季度一般排放口91DA20918番登出罐废气排硫酸雾IlOoIz2.78”33049,41.63IS0.3宿北MF0091MF0058漫出罐SCX002常规演出法1次/季度一般排放口92DA21026#净化摊废气排讷口硫酸雪11001,6.5333049,41.05”150.3常温MF0127MF0094净化短SCX002常婉漫出法1次/季度一般排放口93DA21127#净化罐废气排放口硫酸雾IlOo1,7.21*33049,40.15150.3常温MF0133MFOlOO净化罐SCX002常期浸出法1次/季度一般排放口94DA21217*J三灌底气排液口硫酸雪IlOoIz2.60”33049,41.63150.3常显MF0074MF0041漫出罐SCX002常规漫出法1次/季度一般排放口95DA213德应电炉)球磨废气排放颗粒物IlOoIz11.6433049,41.66150.6常温MFOTlTMF0713球碧机SCX002常规漫出法1次/季度一般排放口96DA21428#:争化灌凌气排液口硫酸雾IlOo1,7